Luljeta Raka, Gordana Bogoeva-Gaceva


A b s t r a c t: The influence of homogeneous and heterogeneous nucleation on crystallization processes of isotactic polypropylene(iPP) and its kinetic and thermodynamic parameters is summarized and discussed, as evaluated by DSC measurements.


polypropylene; isotactic; crystallization behavior; crystal forms; nucleation effects; differential scanning calorimetry (DSC).

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J. Karger-Kocsis: Structure and morphology in: Polypropylene: Structure, blends and composites, Vol.1, Chapman&Hall, London, Weiheim, New York, 1995.

T. Sterzynski, Performance of Plastics, W. Brostow (Ed.), Hanser, Munich/ Cincinnati, Chapter 12, 2001.

B. J. Lee, A. G. McDonald, B. James, Mater. Res. Innovations, 4 (2001), 97–103.

C. Albano, M. Ichazo, J. Gonzales, M. Delgado, R. Poleo, Mater.Res. Innovations, 4 (2001), 284–293.

L. C. Mendes, B. B. B. Martins, M. L. Dias, B. S. Chagas, Mater. Res. Innovations, 4 (2001), 360–364.

R. Sciamanna, G. Arribas, C. Albano, E. Horie and B. Soto, Mater. Res. Innovations, 4 (2001), 311–321.

K. Gadzinowska, E. Piorkowska, Polimery, 48 (2003), 790–799.

F. Auriemma, O. R. de Ballesteros, C. D. Rosa, P. Corradini, Macromolecules, 33 (2000), 8764–8774.

S. C. Tjong, J. S. Shen, R. K. Y. Li, Polymer, 37 (1996), 2309–2316.

A. Turner-Jones, J. M. Aizlewood, D. R. Beckett, Macromoleculare Chemie, 75 (1964), 134–154.

G. Natta, P. Corradini, Nuovo Cimento Suppl., 15 (1960), 40–51.

J. Varga, Angew. Makromol. Chem., 104 (1982), 79–87

B. Fillon, J. C. Wittmann, B. Lotz, A. Thierry, J. Polym. Sci., Part B: Polym. Phys., 31 (1993), 1407–1424.

F. L. Binsbergen, Polymer, 9 (1968), 23–40.

A. Turner-Jones, J. M. Aizlewood, D. R. Beckett, Macromol. Chem., 75 (1964), 134–154.

J. Garbarczyk, D. Paukszta, Polymer, 22 (1981), 562–564.

G. Zhou, Z. He, J. Yu J, Z. Han, G. Shi, Makromol. Chem., 187 (1986), 633–642.

D. S. Filho, C. F. M. Oliviera, Makromol. Chem., 194 (1993), 285–293.

T. Sterzynski, P. Calo, I. Lambla, M. Thomas, Polym. Eng. Sci., 37 (1997), 1917–1927.

X. Zhang, G. Shi, Polymer 35 (1994), 5067–5072.

X. Zhang, G. Shi, Thermochim. Acta, 205 (1992), 235–243.

G. Shi, J. Zhang, Z. Qiu Z, Macromol. Chem., 193 (1992), 583–591.

J. Garbarczyk, T. Sterzynski, D. Paukszta, Polym. Commun., 30 (1989), 153–157.

J. Varga, I. Mudra, G. W. Ehrenstein, J. Appl. Polym. Sci., 74 (1999), 2357–2368.

P. Jacoby, B. H. Bersted, W. J. Kissel, C. E. Smith, J. Polym. Sci. Part B: Polym. Phys., 24 (1986), 461–491.

J. Varga, J. Macromol. Sci. Phys., 41 (2002), 1121–1171.

A. Romankiewicz, PhD Thesis, Poznan University of Technology, Poland (2002).

M. Antonio, C. Marega, R. Saini, I. Camurati, J. Appl. Polym. Sci., 79 (2001), 375–384.

M. Fujiyama, T. Wakino, J. Appl. Polym. Sci., 43 (1991), 97–128.

R. Phillips, G. Herbert, J. News, M. Wolkowicz, Polym. Eng. Sci., 34 (1994), 1731–1743.

C. Silvestre, S. Cimmino, E. Di Pace, Handbook of Polyolefins, 2nd ed, Revised and Expanded, C. Vasile, Ed; Marcel Dekker, New York, 2000.

J. Padden, H. D. Keith, J. Appl. Phys., 30 (1959), 1479–1484.

R.A. Phillips, M.D. Wolkowitz, Structure and Morphology in: Polypropylene Handbook, Ed. E. P. Moore Jr., Hanser, München (1996).

J. Padden, H. D. Keith. J. Appl. Phys., 30 (1959), 1485–1491.

J. Padden, H. D. Keith. J. Appl. Phys., 37 (1966), 4013–4020.

J. Padden, H. D. Keith. J. Appl. Phys., 44 (1973), 1217–1223.

D. R. Norton, A. Keller. Polymer, 26 (1985), 704–716.

F. L. Binsbergen, B. G. M. De Lange, Polymer, 9 (1968), 23–40.

D. T. V. Haeringen, J. Varga, G. W. Ehrenstein, G. J. Vancso, J. Polym. Sci. Part B: Polym. Phys., 38 (2000), 672–681.

J. Varga, J. Mater. Sci., 27 (1992), 2557–2579.

B. Fillon, A. Thierry, J. C. Wittmann, B. Lotz, J. Polym. Sci. Part B: Polym. Phys., 31 (1993), 1407–1424.

S. Brukner, S. V. Meille, V. Pettraccone, B. Pirozzi, Prog. Polym. Sci., 16 (1991), 361–404.

B. Lotz, J. C. Wittmann, A. J. Lovinger, Polymer, 37 (1996), 4979–4992.

S. Z. D. Cheng, B. Lotz, Polymer 46 (2005), 8662–8681.

G. Bogoeva-Gaceva, B. Mangovska, E. Mäder, J Appl. Polym. Sci., 77 (2000), 3107–3118.

A. Grozdanov, G. Bogoeva-Gaceva, J. Serb. Chem. Soc., 63 (6) (1998), 455–466.

G. Bogoeva-Gaceva, A. Janevski, E. Mäder: Polymer, 42 (2001), 4409–4416.

J. J. Zhou, J. G. Liu, S. K. Yan, J. Y. Dong, L. Li, C. M. Chan, J. Schulz, Polymer, 46 (2005), 4077–4087.

L. Raka, G. Bogoeva-Gaceva, Characterization of iPPs From COST P12 Action: Application of DSC And X-Ray Methods, Proceedings of European Polymer Congress (EPF 2007), Portoroz, Slovenia, 2007.

Y. Lin, K. Friedrich, Compos. Sci. Tech., 46 (1993), 187–198.

A. J. Greso, P. J. Phillips, J. Advanced Mater., 25 (1994), 51–60.

C. Y. Yue, W. L. Cheung, J. Mater. Sci. Letters, 12 (1993), 1092–1094.

T. Sterzynski, M. Lambla, H. Crozler, M. Thomas, Adv. Polym. Tech., 13 (1994), 25–36.

A. Thierry, C. Straupe, B. Lotz, J. C. Wittmann, Polym. Commun., 31 (1990), 299–301.

Y. Feng, X. Jin, J. N. Hay, J. Appl. Polym. Sci., 69 (1998), 2089–2095.

A. Romankiewicz, T. Sterzynski, W. Brostow, Polym. Int., 53 (2004), 2086–2091.

A. Janevski, Crystallization, Transcrystallization and Morphology of Modified PP Crystallized in the Presence of Solid Phase, PhD thesis, UKIM, Skopje, 2001.

T. Sterzynski, H. Oysaed, Polym. Eng. Sci., 44 (2004), 352–361.

T. Sterzynski, P. Calo, I. Lambla, M. Thomas, Polym. Eng. Sci., 37 (1997), 1917–1927.

B. Pukanszky, in Polypropylene: An A-Z Reference, J. Karger-Kocsis (Ed), Kluwer Publisher, Dordrecht, 1999, p. 554.

B. Fillon, J. C. Wittmann, B. Lotz, A. Thierry, J. Polym. Sci. Part B: Polym. Phys., 31 (1993), 1383–1393.

B. Fillon, B. Lotz, A. Thierry, J. C. Wittmann, J Polym Sci. Part B: Polym. Phys., 31 (1993), 1395–1405.

G. Bogoeva-Gaceva, A. Janevski, E. Mäder, J. Adhesion Sci. Technol., 14, 3 (2000), 363–380.

G. Bogoeva-Gaceva, A. Grozdanov, J. Serb. Chem. Soc., 71 (1) (2006), 483–499.

G. Bogoeva-Gaceva, A. Janevski, A. Grozdanov, J. Appl. Polym. Sci., 67 (1998), 395–404.

A. Janevski, G. Bogoeva-Gaceva, E. Mäder, J Appl. Polym. Sci., 74 (1999), 239–246.

A. Janevski, G. Bogoeva-Gaceva, J Appl. Polym. Sci., 69 (1998), 381–389.

M. Avella, S. Cosco, G. D. Volpe, M. E. Errico, Adv. Polym. Tech., 24, 2 (2005), 132–144.

W. Leelapornpisit, M. N. Ton-That, F. Perrin-Sarazin, K. C. Cole, J. Denault, B. Simard, J. Polym. Sci. Part B: Polym. Phys., 43 (2005), 2445–2453.

G. Z. Papageorgiou, D. S. Achilias, D. N. Bikiaris, G. P. Karayannidis, Thermochim. Acta, 427 (2005), 117–128.

J. T. Xu, Q. Wang, Z. Q. Fan, Eur. Polym .J., 41 (2005), 3011–3017.

C. A. Mitchell, R. Krishnamoorti, Polymer, 46 (2005), 8796–8804.

K. Wang, Y. Xiao, B. Na, H. Tan, Q. Zhang, Q. Fu, Polymer, 46 (2005), 9022–9032.

Q. Yuan, S. Awate, R. D. K. Misra, Eur. Polym J., 42 (2006), 1994–2003.

W. Xu, M. Ge, P. He, J. Polym Sci. B: Polym. Phys., 40 (2002), 408–414.

A. R. Bhattachryya, T. V. Sreekumar, T. Liu, S. Kumar, L. M. Ericson, R. H. Hauge, R. E. Smalley, Polymer, 44 (2003), 2373–2377.

R. Nowacki, B. Monasse, E. Piorkowska, A. Galeski, J. M. Haudin, Polymer, 45 (2004), 4877–4892.

W. Xu, G. Liang, H. Zhai, Sh. Tang, G. Hang, W.P. Pan, Eur. Polym J., 39 (2003), 1467–1474.

J. Y. Wu, T. M. Wu, W. Y. Chen, Sh. J. Tsai. W. F. Kuo, G. Y. Chang, J. Polym. Sci. B: Polym. Phys., 43 (2005), 3242–3254.

B. P. Grady, F. Pompeo, R.L. Shambaugh, D.E. Resasco, J. Phys. Chem. B, 106 (2002), 5852–5858.

M. Avella, S. Cosco, M.L. Di Lorenzo, E.Di Pace, M.E. Errico, G. Gentile, Eur. Polym. J., 42 (2006), 1548–1557.

L. Mendelkern, Crystallization Kinetics in Polymeric Systems, in Growth and Perfection of Crystals (International Conference on Crystal Growth, Cooperstown, New York, 1958), R. H. Doremus, B. W. Roberts, D. Turnbull (Eds.), John Wiley and Sons, New York, 1958, pp. 467–595.

N. Klein, G. G. Marom, A. Pegoretti, C. Migliaresi, Composites, 26 (1995), 707–712.

C. Wang, C. R. Liu, Polymer, 40 (1999), 289–298.

Y. Cai, J. Peterman, H. Wittich, J. Appl. Polym. Sci., 65 (1997), 67–75.

A. Grozdanov, G. Bogoeva-Gaceva, Polym. Bull., 50 (2003), 397–404.

K. Godowsky, G. L. Slonimsky, J. Polym. Sci., 12 (1974), 1053–1080.

E. Martuscelli, C. Silvestre, G. Abote, Polymer, 23 (1982), 229–237.

B. Monasse, J. Mater Sci., 27 (1992), 6047–6052.

J. Varga, J. Karger-Kocsis, J. Mater. Sci. Letters, 13 (1994), 1069–1071.

J. Varga, J. Karger-Kocsis, J. Polym. Sci.: Part B: Polym. Phys., 34 (1996), 657–670.

J. Varga, J. Karger-Kocsis, Polymer, 36, 25 (1995), 4877–4881.

A. Grozdanov, G. Bogoeva-Gaceva, M. Avella, J. Serb. Chem. Soc., 67, 12 (2002), 843–859.

A. Grozdanov, A. Buzarovska, G. Bogoeva-Gaceva, E. Nedkov, J. Polym. Sci.: Part B: Polym. Phys., 43 (2005), 66–73.

G. Lamberti, Polym. Bull., 52 (6) (2004), 443–449.

B. Monasse, J.M. Haudin, Colloid Polym. Sci., 264 (1986), 117–122.

J. D. Hoffman, Polymer, 23 (1982), 656–670.

E. J. Clark, J.D. Hoffman, Macromolecules, 17 (1984), 878–885.



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